The experiment could be done in a Wolff's bottle fitted
with an exit tube and a long neck funnel. The other end of the exit tube should be bent
and trapped under water. A gas jar of 0.05 Lit. capacity, filled with water has to be
inverted over that end. The hydrogen gas will be collected at the gas jar through
downward displacement of water. The volume of gas ollected can be calculated by
considering the stoichiometries
Mg +
2HCl react to produce MgCl2 + H2 (g)
24 g or one gm-atom
Mg produces 22.4 lit H2 (g) at NTP
0.048 g
Mg produces 22.4*0.048/24 = 0.0448 lit H2 (g) at
NTP
Now at Room temp (higher than NTP), this gas will
expand and the final volume can be obtained from gas law eqn. V/T =
constant
so V1/T1 = V2/T2
or
0.0448/273 = v/298
or v= 0.0448*298/273 = 0.0489 Lit. =
0.05 lit. (approx.)
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